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Number 473 (Story #2), March 3, 2000 by Phillip F. Schewe and Ben Stein
SNOWBALLS SURVIVE IN HELLISH CONDITIONS. Many of the unique and unusual properties of liquid water at ambient conditions are due to the ability of water molecules to form hydrogen bonds, which in turn causes the oxygen atoms to be arranged in a three dimensional diamond-like network. However, under extreme pressures the properties of water can change drastically. For example, although water ice normally melts at 0 C at ambient conditions, at a pressure of 10 Giga-pascals (10,000 atm) water remains "frozen" up to 320 C! New computer simulations carried out at the Lawrence Livermore National Laboratory (Eric Schwegler, 925-424-3098, schwegler@llnl.gov) have explored what happens to the microscopic structure of the compressed liquid, in a region of the phase diagram where experimentally determined structural data do not exist. These simulations indicate that when the liquid is squeezed up to a pressure of 10 GPa, the hydrogen bonds and oxygen network are substantially altered. At this high pressure, each water molecule is close packed and surrounded by 12.9 molecules, as opposed to 4.5 neighbors for ambient conditions. (E.Schwegler, G.Galli, F.Gygi, Phys. Rev. Lett., 13 March /pnu/2000/; figure at Physics News Graphics, also see Select Article.)
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